Hello,
At present psychologists are not routinely employed by the Army as serving personnel - or at least, not that I am aware of!
However the military do employ psychologists as civilians. For these jobs please see the civil service job website. https://www.civilservicejobs.service.gov.uk/csr/index.cgi
If you are a psychologist and you are keen on joining the Army I would advise starting an application on our website, it won't tie you into anything, but you will have access to the recruitment team who will be able to talk through what roles are available and see if there is anything that might suit you.
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